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Incommensurate crystal structure, thermal expansion study and magnetic properties of (dimethylimidazolium)2[Fe2Cl6(?-O)]

Abstract: A thorough characterization of the title compound, (dimim)2[Fe2Cl6(?-O)], consisting of a (?-oxido)-bridged binuclear iron(III) complex and 1,3-dimethylimiazolium (dimim) cation, has been performed using a wide range of techniques. The room temperature disordered crystal structure of this compound transits to an incommensurately modulated crystal structure at 100 K; to our knowledge, the first one found for an imidazolium halometallate complex. The crystal structure was solved in the superspace group P$\bar{1}$(/?/?/?)0 with modulation vector q = 0.1370(10) 0.0982(10) 0.326(2) at 100 K. Variable temperature synchrotron powder x-ray diffraction showed the presence of satellite peaks in addition to the main diffraction peaks up to 208 K. Furthermore, a thermal expansion study was performed with this technique from 100 to 383 K (near of its melting point) adressing questions about the nature and consequences of the ion self-assembly of this (?-oxido)-bridged binuclear iron(III) complex, as well as the molecular motion of the imidazolium cation within the crystalline structure as a response to the temperature effect. Finally, we present a deep magnetic study based on magnetic susceptibility, magnetization and Mössbauer measurements, where the strong antiferromagnetic exchange coupling detected is due to the occurrence of a ?-oxido bridge between the Fe(III), giving rise to an intra-dimeric antiferromagnetic exchange coupling of ?308 cm?1.

 Fuente: Journal of Physics: Materials, Volume 3, Number 1

Editorial: IOP Publishing

 Año de publicación: 2019

Nº de páginas: 14

Tipo de publicación: Artículo de Revista

ISSN: 2515-7639

Proyecto español: MAT2017-89239-C2-(1,2)-P

Autores/as

FABIO SCE

PALMERINA GONZALEZ IZQUIERDO

ISRAEL CANO RICO

BEOBIDE, GARIKOITZ

FABELO, ÓSCAR

VIEIRA, BRUNO J.C.

WAERENBORGH, JOAO C.

VALLCORBA, ORIOL

CASTILLO, ÓSCAR