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Anion-p and halide-halide nonbonding interactions in a new ionic liquid based on imidazolium cation with three-dimensional magnetic ordering in the solid state

Abstract: We present the first magnetic ionic liquid with anion-p interactions, which displays a three-dimensional magnetic ordering below the Néel temperature, TN = 7.7 K. In this material, called Dimim[FeBr4], an exhaustive and systematic study of the magneto-structural correlations, involving crystal and magnetic structure, physical characterization, and first-principles analysis (DFT simulation), was performed.

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Fuente: Inorg. Chem. 2014, 53, 8384-8396

Editorial: American Chemical Society

Año de publicación: 2014

Nº de páginas: 13

Tipo de publicación: Artículo de Revista

DOI: 10.1021/ic500882z

ISSN: 0020-1669,1520-510X

Proyecto español: MAT2011-27573-C04

Url de la publicación: http://pubs.acs.org/doi/abs/10.1021/ic500882z

Leer publicación

Autoría

ABEL GARCIA SAIZ

MANUEL DE PEDRO DEL VALLE

MIGOWSKI, PEDRO

VALLCORBA, ORIOL

FRANCISCO JAVIER JUNQUERA QUINTANA

BLANCO, JESÚS ANGEL

FABELO, ÓSCAR

SHEPTYAKOV, DENIS V.

WAERENBORGH, JOÃO CARLOS BENTES

FERNÁNDEZ-DÍAZ, MARÍA TERESA

RIUS, JORDI

DUPONT, JAIRTON

JESUS ANTONIO GONZALEZ GOMEZ

JESUS MARIA RODRIGUEZ FERNANDEZ

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