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Estimating CO2/N2 permselectivity through Si/Al = 5 small-pore zeolites/PTMSP mixed matrix membranes: influence of temperature and topology

Abstract: In the present work, the effect of zeolite type and topology on CO2 and N2 permeability using zeolites of different topology (CHA, RHO, and LTA) in the same Si/Al = 5, embedded in poly(trimethylsilyl-1-propyne) (PTMSP) is evaluated with temperature. Several models are compared on the prediction of CO2/N2 separation performance and then the modified Maxwell models are selected. The CO2 and N2 permeabilities through these membranes are predicted with an average absolute relative error (AARE) lower than 0.6% taking into account the temperature and zeolite loading and topology on non-idealities such as membrane rigidification, zeolite-polymer compatibility and sieve pore blockage. The evolution of this structure-performance relationship with temperature has also been predicted.

 Autoría: Casado-Coterillo C., Fernández-Barquín A., Valencia S., Irabien Á.,

 Fuente: Membranes 2018, 8(2), 32

 Editorial: MDPI AG

 Fecha de publicación: 16/06/2018

 Nº de páginas: 15

 Tipo de publicación: Artículo de Revista

 DOI: 10.3390/membranes8020032

 ISSN: 2077-0375

 Proyecto español: CTQ2016-76231-C2-1-R ; MAT2015-71842-P