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A group contribution method for the influence of the temperature in the viscosity of magnetic ionic liquids

Abstract: Ionic liquids are widely under research due to their potential properties as solvents. The prediction of their physicochemical properties is an important strategy to achieve a better knowledge for further applications. The present work applies a group contribution method to estimate the viscosity at different temperatures of a new generation of ionic liquids, magnetic ionic liquids (MILs), which are comprised by anions containing transition metal complexes. These new substances have received a high interest due to their response at the presence of a magnetic field. In this study the magnetic ionic liquids are based on the phosphonium cation [P66614]+ with different chain lengths and on the magnetic anions: [GdCl6]3-, [MnCl4]2-, [FeCl4]- and [CoCl4]2-. The database covers a wide range of temperature, 293.15-373.15 K, and viscosity 44-123 500 cP. The modelling estimations show a good agreement with the experimental results, presenting a mean percentage deviation of 7.64%. These results confirm the interest of this model for the estimation of viscosity and the influence of the temperature, which can be extended for a large variety of group combinations in magnetic ionic liquids leading to different applications.

 Autoría: Daniel C.I., Albo J., Santos E., Portugal C.A.M., Crespo J.G., Irabien A.,

 Fuente: Fluid Phase Equilibria, 2013, 360, 29-35

 Editorial: Elsevier

 Fecha de publicación: 25/12/2013

 Nº de páginas: 7

 Tipo de publicación: Artículo de Revista

 DOI: 10.1016/j.fluid.2013.08.031

 ISSN: 0378-3812,1879-0224

 Proyecto español: EUI2008-03857

 Url de la publicación: https://doi.org/10.1016/j.fluid.2013.08.031

Autoría

DANIEL, CARLA ISABEL LOPES

PORTUGAL, CARLA ALEXANDRA MOREIRA

CRESPO, JOÃO PAULO SEREJO GOULÃO