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Stokes and upconverted luminescence in Er3+/Yb3+ -doped Y3Ga5O12nano-garnets

Abstract: The green, red, near-infrared and near-infrared-to-visible upconverted luminescence properties of Er3+/Yb3+ codoped Y3Ga5O12 nanocrystalline powders have been studied using laser spectroscopy. A diffuse reflectance and luminescence spectra confirm that Er3+ and Yb3+ ions occupy the Y3+ sites of the single-phase cubic nano-garnet. Very bright green and red luminescence of the Er3+ ions are detected by the naked eyes, even for a laser power as low as 15 mW, when the Yb3+ ions are excited at 970 nm. The red upconverted emission is more intense than that under direct excitation of the Er3+ ions. The power dependence and the dynamics of the near-infrared-to-green and near-infrared-to-red upconverted emissions show the existence of different two-photon energy transfer upconversion processes. The results here presented indicate that Er3+/Yb3+ codoped Y3Ga5O12 can be a good candidate as an optical nanoheater and nanothermometer in biomedicine applications in the first biological window.

 Autoría: Monteseguro V., Venkatramu V., Rodríguez-Mendoza U.R., Lavín V.,

 Fuente: Dalton Transactions, 2021, 50(27), 9512-9518

 Editorial: Royal Society of Chemistry

 Fecha de publicación: 01/07/2021

 Nº de páginas: 7

 Tipo de publicación: Artículo de Revista

 DOI: 10.1039/d1dt00976a

 ISSN: 1477-9226,1477-9234

 Proyecto español: MAT2016-75586-C4-4-P

 Url de la publicación: https://doi.org/10.1039/D1DT00976A

Autoría

VENKATRAMU, VEMULA

RODRÍGUEZ-MENDOZA, ULISES R.

LAVÍN, VICTOR