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Abstract: Rodlike pi-conjugated molecules in which two OPV fragments are connected through a diacetylene bond self-assemble in aqueous and organic media. Optical spectroscopy and AFM measurements indicated that, in water, strong hydrophobic interactions between pi-cores promote aggregation into robust, uniform micellar structures. In contrast, in apolar solvents, a fibrilar morphology is obtained by coiling of columnar stacks. These stacks are formed in a nucleation-elongation process with degrees of cooperativity of 0.006, that is influenced by the low rotation barriers around the o-bonds in the diacetylene linker.
Fuente: ChemPlusChem, 2019, 84(5), 488-492
Publisher: Wiley-VCH-Verl.
Publication date: 01/05/2019
No. of pages: 5
Publication type: Article
DOI: 10.1002/cplu.201900207
ISSN: 2192-6506
Spanish project: CTQ2017-84727-P
Publication Url: https://doi.org/10.1002/cplu.201900207
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MIGUEL GARCIA IGLESIAS
MAYORAL MUÑOZ, MARÍA JOSÉ
SERRANO MOLINA, DAVID
APARICIO HERNÁNDEZ, FÁTIMA
VÁZQUEZ GONZÁLEZ, VIOLETA
GONZÁLEZ RODRÍGUEZ, DAVID
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