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Phase stability and magnetic properties of a new cobalt(II) coordination polymer based on 2-carboxyethylphosphonate and 1,10'-phenanthroline

Abstract: Co2(HO3PCH2CH2COO)2(C12H8N2)2 has been synthesized from [Co2(HO3PCH2CH2COO)2(C12H8N2)2(?-OH2)](H2O) by thermal treatment (350 °C) under inert atmosphere (N2). The transformation between the initial compound to a red-pink crystalline solid is mediated by an intermediate blue amorphous material. Co2(HO3PCH2CH2COO)2(C12H8N2)2 is stable in air until 440 °C, showing some trends of being magnetically ordered below 2 K.

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Authorship: Fernández-Zapico E., Montejo-Bernardo J., D'Vries R., García J.R., García-Granda S., Rodríguez Fernández J., De Pedro I., Blanco J.A.,

Fuente: Journal of Alloys and Compounds 536S (2012) S507-S510

Publisher: Elsevier Ltd

Year of publication: 2012

No. of pages: 4

Publication type: Artículo de Revista

DOI: 10.1016/j.jallcom.2012.01.012

ISSN: 0925-8388,1873-4669

Spanish project: MAT2010-15094

Publication Url: https://doi.org/10.1016/j.jallcom.2012.01.012

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Authorship

FERNÁNDEZ-ZAPICO, E.

MONTEJO-BERNARDO, J.

VRIES, R. D.

GARCÍA, J. R.

GARCÍA-GRANDA, S.

JESUS MARIA RODRIGUEZ FERNANDEZ

MANUEL DE PEDRO DEL VALLE

BLANCO, J. A.

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