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 Detalle_Publicacion

Synthesis of a Tetracorannulene-perylenediimide That Acts as a Selective Receptor for C60 over C70

Abstract: We report the use of a tetraborylated perylenediimide as starting material for the preparation of a tetracorannulene-perylenediimide that is able to bind up to two fullerene-C60 molecules by host?guest molecular recognition with preference over C70. Titration with fullerene-C60 is followed by a dramatic shift of the aromatic signals in 1H NMR and an initial increase in the fluorescence of the system. By this simple mechanism, fluorogenic sensing of fullerene-C60 is easily accomplished by an unprecedented fluorescent turn-on mechanism.

 Fuente: Org. Lett. 2019, 21, 15, 5803-5807

Editorial: American Chemical Society

 Año de publicación: 2019

Nº de páginas: 5

Tipo de publicación: Artículo de Revista

ISSN: 1523-7052,1523-7060

Proyecto español: CTQ2013- 41067-P ; CTQ2015-71353-R ; PGC2018-099470-B-100

Url de la publicación: https://doi.org/10.1021/acs.orglett.9b01729

Autores/as

GARCÍA-CALVO, VÍCTOR

CUEVAS, JOSÉ V.

BARBERO, HÉCTOR

FERRERO, SERGIO

ÁLVAREZ, CELEDONIO M.

DÍAZ DE GREÑU, BORJA

GARCÍA-CALVO, JOSÉ

TORROBA, TOMÁS