Abstract: The double carbonate BaCa(CO3)2 holds potential as host compound for carbon in the Earth?s crust and mantle. Here, we report the crystal structure determination of a high-pressure BaCa(CO3)2 phase characterized by single-crystal X-ray diffraction. This phase, named post-barytocalcite, was obtained at 5.7 GPa and can be described by a monoclinic Pm space group. The barytocalcite to post-baritocalcite phase transition involves a significant discontinuous 1.4% decrease of the unit-cell volume, and the increase of the coordination number of 1/4 and 1/2 of the Ba and Ca atoms, respectively. High-pressure powder X-ray diffraction measurements at room- and high-temperatures using synchrotron radiation and DFT calculations yield the thermal expansion of barytocalcite and, together with single-crystal data, the compressibility and anisotropy of both the low- and high-pressure phases. The calculated enthalpy differences between different BaCa(CO3)2 polymorphs confirm that barytocalcite is the thermodynamically stable phase at ambient conditions and that it undergoes the phase transition to the experimentally observed post-barytocalcite phase. The double carbonate is significantly less stable than a mixture of the CaCO3 and BaCO3 end-members above 10 GPa. The experimental observation of the high-pressure phase up to 15 GPa and 300 ºC suggests that the decomposition into its single carbonate components is kinetically hindered.

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